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Photochemical reduction of carbon dioxide using nickel tetraazamacrocycles

โœ Scribed by Craig, Carl A.; Spreer, Larry O.; Otvos, John W.; Calvin, Melvin.


Book ID
119954450
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
543 KB
Volume
94
Category
Article
ISSN
0022-3654

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โœ Etsuko Fujita ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 142 KB

Transition-metal complexes, CoHMD 2 + (HMD = 5, 7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) and Ru(bpy) 2 (CO)X n + (bpy= 2,2%-bipyridine, X =CO, Cl, H, etc.), mediate electron transfer in the photochemical reduction of CO 2 . The thermodynamics and kinetics of CO 2 binding t