Photochemical rearrangements of highly functionalized longipinene derivatives
✍ Scribed by Pedro Joseph-Nathan; Myriam Meléndez-Rodríguez; Carlos M. Cerda-García-Rojas; César A.N. Catalan
- Book ID
- 103407914
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 233 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
The photochemical rearrangement of benzonorcaradiene derivatives has been attracting interests in recent years, and studied by several workers, but neither study on the stereochemical course of the rearrangement nor the reaction with 7-alkyl substituted derivatives was reported. 1,2,3
## Abstract A series of di‐ and trisubstituted cyclopropyl ketones **11** were prepared by irradiation of ketones **3** and **5**, which bear a leaving group adjacent to the carbonyl C‐atom. The required ketones **3** could be easily synthesized either by functionalization of ketones **1** with a h