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Photochemical rearrangement of benzonorcaradiene derivatives

✍ Scribed by Masahiko Kato; Masanori Kawamura; Yukio Okamoto; Toshio Miwa


Book ID
104236559
Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
187 KB
Volume
13
Category
Article
ISSN
0040-4039

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✦ Synopsis


The photochemical rearrangement of benzonorcaradiene derivatives has been attracting interests in recent years, and studied by several workers, but neither study on the stereochemical course of the rearrangement nor the reaction with 7-alkyl substituted derivatives was reported. 1,2,3


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Rearrangement reactions are ubiquitous and they can occur both in the ground state as well as in the excited state. [1] The photochemical properties of stilbene-type compounds are well-documented [2Β±4] and major reactions include cis Β± trans isomerization, exciplex reactions, addition, and oxidative