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Photochemical Rearrangement of a Steroidal α,β-Epoxylactone. Photochemical reactions, XI [1]

✍ Scribed by María Jesús Caus; Antonio Cánovas; Juan-Julio Bonet

Publisher: John Wiley and Sons
Year: 1980
Tongue: German
Weight: 284 KB
Volume: 63
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19800630218

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✦ Synopsis

Abstract

The UV. irradiation of 17β‐acetoxy‐4α, 5α‐epoxy‐2‐oxaandrostan‐3‐one (7) yields 17β‐acetoxy‐2‐oxa‐10(5 → 4)abeo‐4ζ (H)‐androsta‐3,5‐dione (11). A non‐photochemical synthesis of 11, proceeding in lower yield, is also described.

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