Vitamin B 12 enzymes, involving the cobalt species as a catalytic center, mediate various isomerization reactions accompanied by carbon-skeleton rearrangements. In order to simulate the catalytic functions of vitamin B 12 as exerted in the hydrophobic active sites of enzymes concerned, we have been
Photochemical reactions of vitamin B12 derivatives
✍ Scribed by Bernhard Kräutler
- Book ID
- 113138494
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 359 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0010-8545
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## Dedicated to Professor Karl Grubmayr on the occasion of his 60th birthday Vitamin B 12 (cyanocobalamin, 1) features a cobalt corrin and a nucleotide functionality in the stable, "base-on" form, [1][2][3] a hallmark of Natures "most beautiful" cofactors. [4] The intramolecular coordination of th