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Photochemical reactions of phosphaalkenes

✍ Scribed by Abdekader Meriem; Jean-Pierre Majoral; Monique Revel; Jacques Navech

Book ID: 104217270
Publisher: Elsevier Science
Year: 1983
Tongue: French
Weight: 212 KB
Volume: 24
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)81820-1

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✦ Synopsis

REVEL and Jacques NAVECH* E.R.A. 926, Synthese structure et reactivite de m)l&_ules phosphorees Universite Paul Sabatier, 113 route de Narbonne 31062 TOULOUSE (FRANCE) . Summary : Photolysis of phosphaalkenes leads to an inversion of polarity of the phosphorus carbon double bond and to a cleavage into transient phosphinidene and carbene ; unexpected alcoholysis of a PITT-C bond and the [4+2] cycloaddition of a linear phosphaalkene on a diene are also reportea. Very few papers have described the photochemical behavior of phosphorus derivatives with a phosphorus carbon double bond. Most of them are concerned with the irradiation of phosphorus ylide Ph3P=CRR1 '.

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