Photochemical reactions of N-alkylanilines
โ Scribed by Ogata, Yoshiro.; Takagi, Katsuhiko.
- Book ID
- 126047475
- Publisher
- American Chemical Society
- Year
- 1970
- Tongue
- English
- Weight
- 552 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Irradiation of 4-chloroanilines in the presence of alkenes gives 4-(2%-chloroalkyl)-anilines. When the irradiation is carried out in the presence of NaBH 4 , 4-alkylanilines are obtained directly. The reaction appears to occur via the corresponding phenyl cation.
Dialkylimidazolidinetriones undergo intramolecular hydrogen abstraction on irradiation to give elimination, intramolecular disproportionation, and cyclization products. Imidazolidinetrione (parabanic acid) which possesses three carbonyl groups and two nitrogen atoms may be viewed as a composite of