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Photochemical conversion of 4-chloroaniline into 4-alkylanilines

โœ Scribed by Paolo Coppo; Maurizio Fagnoni; Angelo Albini

Book ID
104230775
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
68 KB
Volume
42
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Irradiation of 4-chloroanilines in the presence of alkenes gives 4-(2%-chloroalkyl)-anilines. When the irradiation is carried out in the presence of NaBH 4 , 4-alkylanilines are obtained directly. The reaction appears to occur via the corresponding phenyl cation.

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