N-benzoyl and 4-acetylaniline moieties are coplanar. The aromatic ring of the other benzoyl is twisted with respect to the attached 4-acetylaniline. The molecular structure is maintained by intramolecular CÐHÁ Á ÁO and NÐHÁ Á ÁO interactions, and the packing is stabilized by a weak CÐ HÁ Á ÁO intera
N,N-Dibenzoyl-4-chloroaniline
✍ Scribed by Usman, Anwar ;Razak, Ibrahim Abdul ;Fun, Hoong-Kun ;Chantrapromma, Suchada ;Tian, Jing-Zhi ;Zhang, Yan ;Xu, Jian-Hua
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 213 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 183 K Mean '(C±C) = 0.004 A Ê R factor = 0.054 wR factor = 0.131 Data-to-parameter ratio = 13.4
For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
Molecules of the title compound, C~14~H~12~ClNO~2~, are linked by one C—H...Cl hydrogen bond, forming a __C__(13) chain running parallel to the [010] direction; these chains are linked by further C—H...π and C—H...Cl hydrogen bonds, resulting in a three-dimensional network structure.
In the title compound, C 15 H 15 Cl 2 N 2 O + ÁBr À , the angle between the least-squares planes of the dichlorophenyl moiety and the pyridine ring is 20.23 (9) . The molecular packing is mainly in¯uenced by intermolecular CÐHÁ Á ÁBr hydrogen-bond interactions. The molecules form an extended chain a
Single-crystal X-ray study T = 273 K Mean '(C±C) = 0.003 A Ê R factor = 0.040 wR factor = 0.112 Data-to-parameter ratio = 17.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.003 A Ê R factor = 0.033 wR factor = 0.081 Data-to-parameter ratio = 13.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.