Photochemical reaction of aromatic nitro compounds with aromatic amines
β Scribed by Masaaki Takami; Teruo Matsuura; Isao Saito
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 117 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Reduction of aromatic nitro compounds to amines with hydriodic acid was reinvestigated. Under a milder non-refluxing condition (at 90Β°C for 2-4 h), the reduction proceeded efficiently with excellent chemoselectivity without affecting other functional groups including nitrile, ester, halide, carbonyl
A simple method for the reduction of aromatic nitro compounds to aromatic amines was developed using samarium and catalytic amounts of iodine.
## Abstract Aromatic amines were prepared in good yields by a novel reduction of aromatic nitro compounds with tellurium metal in nearβcritical water at 275Β°C.