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Photochemical oxyfluoroalkylation of styrenes by the addition of perfluoroalkyl radicals in an atmosphere of oxygen

✍ Scribed by Masato Yoshida; Masanori Ohkoshi; Nobuyuki Aoki; Yuki Ohnuma; Masahiko Iyoda

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
224 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

The photochemical reaction of perfluoroalkyl iodide with o~-methylstyrene and related compounds in the presence of hexabutylditin under oxygen atmosphere produces the fluoroalkylated alcohols in good yields. The reaction was photochemicaily initiated, and proceeded via a radical chain mediated by the ditin.

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