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Free-radicals in the oxidation and halogenation of alkanes by dimethyldioxirane: an oxygen rebound mechanism

โœ Scribed by Francesco Minisci; Lihua Zhao; Francesca Fontana; Anna Bravo


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
204 KB
Volume
36
Category
Article
ISSN
0040-4039

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Computational modeling of the mechanisms
โœ D. L. Allara; D. Edelson; K. C. Irwin ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 766 KB

A general computational method for obtaining complete solutions of time-dependent kinetic equations has been developed and applied to free radical-initiated reactions of alkanes with oxygen. The method has been applied to the low-temperature, peroxideinitiated oxidations of isobutane and isopentane.