Photochemical isomerization of N-alkoxyisosulfobenzimides
β Scribed by Louis A. Levy
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- French
- Weight
- 137 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0040-4039
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In connection with studies of the mechanism of a numbsr of photochemical reactions, particularly of structu&.ly interesting asaturated ketones, we have studied the photolysis of dehgdronomae@W, blcyclo[2.2.l]bept-5-en-2-one (I). We were led to at&y this partictim compomd in order to determiue what r
## Abstract Allβ__trans__βRetinoic acid [11,12β^3^H(N)] was photochemically isomerized using a fluorescent source to afford a mixture of isomeric retinoic acids, from which 9β__cis__βretinoic acid[11,12β^3^H(N)] was isolated by reversedβphase HPLC. The identity of 9β__cis__βretinoic acid [11, 12β^3