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Photochemical hole-burning down to 0.3 K in organic amorphous systems

✍ Scribed by H.P.H. Thijssen; R.E. Van Den Berg; S. Völker

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 561 KB
Volume: 103
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87066-3

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✦ Synopsis

The homogeneous hnewidth (I',,~~) of the O-O St + So transitIon of free-base porphin (HzP) m polyethylene and Iglycerol has been studled via photochemical hole-bummg down to 0.3 K On lowermg the temperature the rhom a T1-3 relatton previously observed goes over to a linear dependence at the point where rhom = 60 hlHz At = 0 3 ii rhom III HzP m polyethylene reaches the hfetime-Iunited value of = 10 MHz Two recently proposed models that attempt IO e_~plam these results are dwzussed.

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