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Photochemical cycloaddition of 1,3-diacetoxy-2-propanone to (trimethylsilyloxy)ethylene

✍ Scribed by Younosuke Araki; Jun-ichi Nagasawa; Yoshiharu Ishido


Book ID
108307783
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
469 KB
Volume
91
Category
Article
ISSN
0008-6215

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The cycloaddition reaction of Ξ±-oxo sulf
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## Abstract The cycloaddition reaction of α‐oxo sulfines with 2‐(trimethylsiloxy)‐1,3‐dienes, leading ultimately to thiacyclohexanone __S__‐oxides (alternatively named as thianone __S__‐oxides or perhydrothiapyranone __S__‐oxides) is described. 1‐Oxo‐2‐thioxo‐indane __S__‐oxide 2a, and several α‐ox