Diarylthioketones 1,2 , thiophosgene3, and thione carbonates 4 react with substituted alkenes under photochemical conditions to give thietanes and in some cases, 1,4-dithianes. It is known that thioparabanates, A, undergo photoreduction in ethanolic solution5. However, the formation of a small amoun
Photochemical [3 + 2] cycloaddition of 2-cyanochromone to olefins
โ Scribed by Isao Saito; Koji Shimozono; Teruo Matsuura
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 162 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
The [2+2] Photocycloaddition of different cyclic enones to (5R)-5-menthyloxy-2[5H]furanone is investigated. The diastereoselectivity relative to the chiral acetal centre and the regio and the exo/endo ratios of the products have been determined. By variation of the structure of cyclic enones, the di
## Abstract Selected [2+2]โcycloadditions of three alkylvinylketenes **2** to one monoโ and seven dialkylโolefins **3** yielded eleven 2โalkylโ2โvinylcyclobutanones **4** __(Tables 1__ and __2).__ Three methods were compared, all involving __in situ__ generation of the ketenes **2** by HClโeliminat