Irradiating cyclohexenones containing an olefinic side chain under electron transferconditions (PET) leads to new spirocyclic products 3, as well as [2+2]-cycloaddition products 2. A new reductive cyclobutane ring opening allows photochemical conversion of cyclobutanes 2 to spirocyclic compounds 3.
โฆ LIBER โฆ
Photochemical chlorodecarboxylation via an electron transfer mechanism
โ Scribed by Okada, Keiji; Okamoto, Kazushige; Oda, Masaji
- Book ID
- 118066055
- Publisher
- The Royal Society of Chemistry
- Year
- 1989
- Tongue
- English
- Weight
- 186 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0022-4936
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