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Photochemical Behavior of N2-Complexes: Photoluminescence of trans-(N2)2W(diphos)2 and trans-(CO)2W(diphos)2

✍ Scribed by Albert Caruana; Priv.-Doz. Dr. Horst Kisch

Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
243 KB
Volume
18
Category
Article
ISSN
0044-8249

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✦ Synopsis

The first photoluminescing dinitrogen complex trans‐(N~2~)~2~W(diphos)~2~ (1) is also the first transition‐metal(o) compound to show a structured emission spectrum. These finding are of considerable significance for the photochemical reduction of complexed N~2~.

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Photochemisches Verhalten von N2-Komplexen: Photolumineszenz von trans-(N2)2W (diphos)2 und trans-(CO)2W (diphos)2
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**Der erste photolumineszierende Distickstoffkomplex** __trans__‐(N~2~)~2~ W(diphos)~2~ (__1__) zeigt auch als erste Übergangsmetall(0)‐Verbindung ein strukturiertes Emissionsspektrum. Diese Befunde sind für die photochemische Reduktion von komplexiertem N~2~ von großer Bedeutung.

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