Ab initio calculations of all indirect spin-spin coupling constants in the cis and tvans isomers of N,F, are discussed. The accuracy of the theoretical results is estimated and their values are compared with recent experimental data. Ab initio calculated values can be helpful in the analysis of the
ChemInform Abstract: Dinitrogen Difluoride Chemistry. Improved Syntheses of cis- and trans-N2F2, Synthesis and Characterization of N2F+Sn2F9-, Ordered Crystal Structure of N2F+Sb2F11-, High-Level Electronic Structure Calculations of cis-N2F2, trans-N2F2, F2N=N, and N2F+, and Mechanism of the trans—cis Isomerization of N2F2.
✍ Scribed by Karl O. Christe; David A. Dixon; Daniel J. Grant; Ralf Haiges; Fook S. Tham; Ashwani Vij; Vandana Vij; Tsang-Hsiu Wang; William W. Wilson
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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The complexes [Ag(g 2 -N 6 S) 2 ](PF 6 ), N 6 S = 1methyl-2-(methylthiomethyl)-1H-benzimidazole, mmb (complex 1) or 1-methyl-2-(tert-butylthiomethyl)-1H-benzimidazole, mtb (complex 2), and [Ag(l,g 2 -mmb)(l,g 2 -O 2 PF 2 )] (complex 3) were synthesized and characterized by X-ray crystallography. Lon