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Photochemical approach to 4,5-dioxoaporphine alkaloids. The total synthesis of pontevedrine

✍ Scribed by Luis Castedo; Ramón J. Estévez; José M. Saá; Rafael Suau


Book ID
112126908
Publisher
Journal of Heterocyclic Chemistry
Year
1982
Tongue
English
Weight
384 KB
Volume
19
Category
Article
ISSN
0022-152X

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✍ Rafael Suau; Juan Manuel López-Romero; Rodrigo Rico 📂 Article 📅 1996 🏛 Elsevier Science 🌐 French ⚖ 230 KB

Cyelization of biaD:lacetamides to their phenanthrene derivatives is promoted by oxalyl ehloride/stannyl chloride. The reaction proceeds with a second cyclization in which the oxalyl fragment acts as an t~-dicarlx~vI transfer agent to give 4,5-dioxoaporphine alkaloids in a single step. This double c