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Photochemical and Electrochemical Properties of Zinc Chlorin−C 60 Dyad as Compared to Corresponding Free-Base Chlorin−C 60 , Free-Base Porphyrin−C 60 , and Zinc Porphyrin−C 60 Dyads

✍ Scribed by Fukuzumi, Shunichi; Ohkubo, Kei; Imahori, Hiroshi; Shao, Jianguo; Ou, Zhongping; Zheng, Gang; Chen, Yihui; Pandey, Ravindra K.; Fujitsuka, Mamoru; Ito, Osamu; Kadish, Karl M.


Book ID
120405016
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
124 KB
Volume
123
Category
Article
ISSN
0002-7863

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The synthesis of the cyclophane-type molecular dyads 1 and 1 . Zn was accomplished by Bingel macrocyclization of porphyrin-tethered bis-malonates 5 or 5 . Zn, respectively, with C 60 ( Scheme). In these macrocycles, the doubly bridged porphyrin adopts a close, tangential orientation relative to the