ChemInform Abstract: Synthesis, and Optical and Electrochemical Properties of Cyclophane-Type Molecular Dyads Containing a Porphyrin in Close, Tangential Orientation Relative to the Surface of trans-1 Functionalized C60.

Synthesis, and Optical and Electrochemic

Synthesis, and Optical and Electrochemical Properties of Cyclophane-Type Molecular Dyads Containing a Porphyrin in Close, Tangential Orientation Relative to the Surface of trans-1 Functionalized C60. Preliminary Communication

✍ Jean-Pascal Bourgeois; François Diederich; Luis Echegoyen; Jean-François Niereng 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 170 KB 👁 1 views

The synthesis of the cyclophane-type molecular dyads 1 and 1 . Zn was accomplished by Bingel macrocyclization of porphyrin-tethered bis-malonates 5 or 5 . Zn, respectively, with C 60 ( Scheme). In these macrocycles, the doubly bridged porphyrin adopts a close, tangential orientation relative to the