Photochemical Addition of 2,2,2-Trifluoroethanol to Benzonitrile and p -, m -, and o -Methylbenzonitrile
โ Scribed by Foster, Jennifer; Pincock, Alexandra L.; Pincock, James A.; Thompson, Kim A.
- Book ID
- 127122831
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 255 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Phenyhnagnesium bromide and methyhnagnesium bromide in tetmhydrofuran undergo a regiose lective addition to the cyan0 group of the two title compounds. Phenyllithium and methyllithhnn add selectively to the azomethine portion of 2-[(benzylidene)anko]benzonitrile, but to the cyano group of Z[(dipheny
The title reaction has been studied with 2-methoxypropene, (E)-cyclooctene, ethoxyethene, 1,3-cyclopentadiene, 3methylenecyclohexene, styrene and isoprene as the olefinic substrates. This sequence is one of decreasing reactivity of the substrates towards 2-oxido-2-cyclopenten-1-ylium (1) if [4 + 3]