Photocatalytic Degradation of Dicofol and Pyrethrum with Boric and Cerous Co-doped TiO2 under Light Irradiation
β Scribed by Lifen GONG; Jing ZOU; Jinbin ZENG; Wenfeng CHEN; Xi CHEN; Xiaoru WANG
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 247 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0256-7660
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β¦ Synopsis
Boric and cerous co-doped nano titanium dioxide (B/Ce co-doped TiO 2 ) was synthesized using a sol-gel technique, which involved the hydrolyzation of tetrabutyl titanate with the addition of boric acid and cerous nitrate. The B/Ce co-doped TiO 2 was employed for the photocatalytic degradation of dicofol, cyfluthrin and fenvalerate under light irradiation. XRD, TEM, FT-IR and UV-Vis DRS methods were used to characterize the crystalline structure. Experimental results showed that only the anatase signal phase was found for B/Ce co-doped TiO 2 , but multiplicate phases, including anatase, rutile and less brookite phases, were identified both in the pure TiO 2 nanoparticles and Ce-doped TiO 2 nanoparticles. The band gap value of B/Ce co-doped nano TiO 2 was narrower than that of undoped nano TiO 2 . Compared to undoped TiO 2 , a stronger absorption in the range of 420 to 850 nm was found for B/Ce co-doped nano TiO 2 , which presented a higher photocatalytic activity in the degradation of dicofol, cyfluthrin and fenvalerate than both Ce doped nano TiO 2 and pure nano TiO 2 under the same light irradiation.
Keywords boric and cerous co-doped, titanium dioxide, pesticide, photocatalytic degradation Boric and cerous co-doped
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