## Abstract The title compounds are the first examples of solventβfree oxide methanesulfonates of Mo, U, Re, and V.
Photoabsorption spectra of gaseous CH3SO2Cl, CCl3SCl, SO2ClF and (CH3O)2SO
β Scribed by R. Kozlowski; G.B. Fazekas; M.C. Withiam; K. Bloomer; R. Sampson; T.D. Allston; G.A. Takacs
- Publisher
- Elsevier Science
- Year
- 1982
- Weight
- 444 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0047-2670
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π SIMILAR VOLUMES
Methylperoxy radicals were generated by the flash photolysis of azomethane-oxygen mixtures. The observed broadband spectrum of the CH302 radical is similar, but not identical to those reported previously. The CH:302 decay followed second-order kinetics a t high CH:jOz concentrations with k4, = (2.5
Mixtures of Cl:!, CH4, and 0 2 were flash photolyzed a t room temperature and pressures of -60-760 Torr to produce CH3O2. The CH3O2 radicals decay by the second-order process (6) 2CH302products with k g = (3.7 f 0.3) X cm3/sec in good agreement with other studies. This value ignores any removal by s