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Photo-fries reaction of 1-naphthyl cinnamate

โœ Scribed by T Jayachandran; T Manimaran; V T Ramakrishnan

Book ID
112925221
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1986
Tongue
English
Weight
216 KB
Volume
97
Category
Article
ISSN
0253-4134

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1-Naphthyl phenyl acylates upon irradiation in solution yield eight products via b-cleavage process. However, excitation of these molecules as included in g-cyclodextrin results in a single product (>95%). This medium dependent product selectivity is attributed to conformational and translational re