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Cyclodextrin-Mediated Regioselective Photo-Fries Reaction of 1-Naphthyl Phenyl Acylates.

✍ Scribed by Smriti Koodanjeri; Ajit R. Pradhan; Lakshmi S. Kaanumalle; V. Ramamurthy


Publisher
John Wiley and Sons
Year
2003
Weight
105 KB
Volume
34
Category
Article
ISSN
0931-7597

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Cyclodextrin-mediated regioselective pho
✍ Smriti Koodanjeri; Ajit R Pradhan; Lakshmi S Kaanumalle; V Ramamurthy πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 143 KB

1-Naphthyl phenyl acylates upon irradiation in solution yield eight products via b-cleavage process. However, excitation of these molecules as included in g-cyclodextrin results in a single product (>95%). This medium dependent product selectivity is attributed to conformational and translational re