Phosphorus/buckminsterfullerene intercalation compounds, C60(P4)2
β Scribed by I.Wyn Locke; Adam D. Darwish; Harold W. Kroto; Kosmas Prassides; Roger Taylor; David R.M. Walton
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 370 KB
- Volume
- 225
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
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A novel crystalline compound has been made by combining the two elements, carbon and phosphorus,that form isolated cage allotropes. The material, C&P&, which consists of disordered tetrahedral P, molecples intercalated in a hexagonal C, crystal lattice has been prepared by both gas-solid reaction and co-precipitation from benzene solution.
π SIMILAR VOLUMES
Electronic and vibrational spectroscopy were used to study the electronic processes in charge-transfer complexes of fullerene and tetraphenylphosphonium or tetraphenylarsenium halides. These fully ionic crystalline complexes feature the occurrence of C60 monoanions and the onset of charged phonon be
The structure of the compound was deduced from the 119Sn and 31P NMR spectra 3 and it was shown to be a structural analogue of the hetero-nortricyclene The apical phosphorus atom P 4 S 3 . exhibits an extremely negative 31P chemical shift of [554.65 ppm, and the basal phosphorus atoms also resonat