Phosphorus Monoxide (PO) as Complex Ligand
✍ Scribed by Prof. Dr. Otto J. Scherer; Dr. Jürgen Braun; Dipl.-Chem. Peter Walther; Dipl.-Chem. Cert Heckmann; Dr. Gotthel Wolmershäuser
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- English
- Weight
- 578 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
Alkali metal bis(trimethylsilyl)phosphanides react with different halogenophosphorus compounds to form multiple P-P bonds. ['] The alkali metal phosphanide serves as a reagent for metalation of silylphosphorus functionalities with the elimination of P(SiMe,), and as a source for the central phospho
## on the occasion of his 65th hirthday The recently reported successful stabilization of cyclo-As5 and cyclo-P, ("hexaphosphabenzene") as bridge ligand ("middle deck") in the triple-decker complexes l"] and 2") respectively, signaled the possibility of also stabilizing cvclo-P, in the same way.[3
## Four new metal ion complexes with phosphatrane ligands have been isolated and characterized including AuBr 3 (SP(OCH ). The phosphatranes are examples of hypervalent phosphorus ligands which are bound through oxygen or sulfur to the metal ion. These complexes are unique models for proposed inte