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Hypervalent phosphorus compounds as ligands

✍ Scribed by Janet R. Morrow; Paul Savino; Luyun Huang; Anthony Perri

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
146 KB
Volume
9
Category
Article
ISSN
1042-7163

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✦ Synopsis

Four new metal ion complexes with phosphatrane ligands have been isolated and characterized including AuBr 3 (SP(OCH

). The phosphatranes are examples of hypervalent phosphorus ligands which are bound through oxygen or sulfur to the metal ion. These complexes are unique models for proposed intermediates in metal ion promoted phosphate ester substitution reactions.

📜 SIMILAR VOLUMES

Dihalo derivatives of 3-coordinate hyper
Dihalo derivatives of 3-coordinate hypervalent phosphorus compounds
✍ Anthony J. Arduengo III; Johannes Breker; Fredric Davidson; Michael Kline 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 722 KB

## Abstract The preparation of 1,1‐difluoro‐3,7‐di‐tert‐butyl‐2,8‐dioxa‐1‐phosphabicyclo[3.3.0]octa‐3,6‐diene (Dit‐BuADPO·F~2~)from hexafluoropropylene oxide (HFPO) and 3,7‐di‐tert‐butyl‐2,8‐dioxa‐1‐phosphabicyclo[3.3.0]octa‐2,4,6‐triene (DitBuADPO) is described. The solid state structure of DitBuA

Phosphorus Monoxide (PO) as Complex Liga
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Complexes Containing Phosphorus and Arse
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Alkali metal bis(trimethylsilyl)phosphanides react with different halogenophosphorus compounds to form multiple P-P bonds. ['] The alkali metal phosphanide serves as a reagent for metalation of silylphosphorus functionalities with the elimination of P(SiMe,), and as a source for the central phospho