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Phosphorus Analogs of Bipyridines: Their Synthesis and Coordination Chemistry

✍ Scribed by Mathey, François ;Le Floch, Pascal


Publisher
Wiley (John Wiley & Sons)
Year
1996
Tongue
English
Weight
460 KB
Volume
129
Category
Article
ISSN
0009-2940

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✦ Synopsis


The synthesis and coordination chemistry of 2-(2-pyridyl)-been characterized by X-ray analysis. Ruthenium, mangaphosphinines and 2,2'-biphosphinines are reviewed. A note-nese and rhenium chelates were also obtained. With worthy series of homoleptic complexes of 4,4',5,5'-tetrame-Mn,(CO)lo, a (tmbp)-Mn,(CO), complex is formed where thyl-Z,2'-biphosphinine (tmbp) with Cr(O), Mo(O), Wo(0) and tmbp acts as an eight electron donor. Ni(0) are described. A [Cu(bpy)(tmbp)]' cationic polymer has


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