Synthesis, Structure, and Coordination Chemistry of Diisocyanomethane
✍ Scribed by Dr. Jürgen Buschmann; Thilo Bartolmäs; Priv.-Doz. Dr. Dieter Lentz; Prof. Dr. Peter Luger; Ingo Neubert; Matthias Röttger
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 400 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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## Abstract The complete manuscript of this communication appears in: __Angew. Chem. Suppl. 1982__, 269. DOI:10.1002/anie.198202690
Four new cavitand ligands, modified at the lower rim with cyano and pyridyl functional groups, have been synthesized and their coordinative behaviour toward transition metal ions has been explored. The outcome of the self-assembly of these compounds in the presence of different metal precursors is b
The dichlorodihydridoruthenium (IV) compound [RuH 2 Cl 2 -were obtained. The phenylvinylidene complex [RuCl 2 (=C= CHPh)(PCy 3 ) 2 ] (15) was prepared from phenylacetylene and (PiPr 3 ) 2 ] (4) was prepared from [RuCl 2 (C 8 H 12 )] n (3), PiPr 3 , and H 2 in 2-butanol via the chlorohydridoruthenium