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Phosphorus-31 NMR and kinetic studies of the formation of ortho-, pyro-, and triphosphato complexes of cis-dichlorodiammineplatinum(II)

✍ Scribed by Bose, Rathindra N.; Viola, Ronald E.; Cornelius, Richard D.


Book ID
126172093
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
921 KB
Volume
106
Category
Article
ISSN
0002-7863

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Phosphorus-31 and platinum-195 NMR studi
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## Abstract Carboxylato‐bridged dinuclear platinum(II) complexes of the type [Pt~2~X~2~(μ‐OOCRβ€²)~2~(PR~3~)~2~] [X = Cl, I; Rβ€² = CH~3~, CF~3~; PR~3~ = PEt~3~^n^, PPr~3~^n^, PBu~3~^n^, PMe~2~Ph, PMePh~2~, PPh~3~, P(__p__‐Tol)~3~] were prepared and investigated by ^31^P and ^195^Pt NMR spectroscopy. T