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Phosphorus-31 and platinum-195 NMR studies of carboxylato-bridged dinuclear platinum(II) complexes

✍ Scribed by S. Kannan; V. K. Jain

Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 294 KB
Volume: 28
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260281202

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✦ Synopsis

Abstract

Carboxylato‐bridged dinuclear platinum(II) complexes of the type [Pt~2~X~2~(μ‐OOCR′)~2~(PR~3~)~2~] [X = Cl, I; R′ = CH~3~, CF~3~; PR~3~ = PEt~3~^n^, PPr~3~^n^, PBu~3~^n^, PMe~2~Ph, PMePh~2~, PPh~3~, P(p‐Tol)~3~] were prepared and investigated by ^31^P and ^195^Pt NMR spectroscopy. The NMR data indicate that there is considerable platinum‐platinum interaction in these complexes.

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