Phosphoranyl radicals: An esr study of Ph3PBr Trapped in a single crystal
β Scribed by T. Berclaz; M. Geoffroy; L. Ginet; E.A.C. Lucken
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 343 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Ph~3~Γ sBr is trapped in an Xβirradiated single crystal of Ph~3~As^+^CH~3~Br^β^. The gβtensor, the ^75^As and ^79^Br magnetic hyperfine tensors and the ^79^Br quadrupolar interaction tensor are obtained at room temperature. They show that the structure of this arsoranyl radical is intermediate betwee
## Received 4 I)ect?mbcr 1975 X-irradiation of sin@ crystals of triphcnylgcrmane yields the triphenylgcrmyl radical (CgHs)&e. The 73Ge hypcrfine coupling, parameters show that, as expected, the radical is non-planar and sirnilsr to (Ci,H5)3$ and (CbHs)3PT, Quadrupole'coupling effects were not obse