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Phosphoramidite Ligands in Iridium-Catalyzed Allylic Substitution

✍ Scribed by Damien Polet; Alexandre Alexakis; Karine Tissot-Croset; Clemence Corminboeuf; Klaus Ditrich

Publisher
John Wiley and Sons
Year
2006
Weight
42 KB
Volume
37
Category
Article
ISSN
0931-7597

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Phosphoramidite Ligands in Iridium-Catal
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## Abstract A new phosphoramidite ligand was used in the iridium‐catalyzed allylic substitution reaction. This permitted high regio‐ and enantioselectivities on a wide variety of substrates and nucleophiles. Because of the stereospecificity of the reaction obtained by using branched substrates, a k

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