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Phosphoramidate-Mediated Conversion of Carbonyl Ligands into Isocyanide Ligands: A New Approach to Chiral Isocyanide Ligands

✍ Scribed by Susan E. Gibson; Hasim Ibrahim; Corinne Pasquier; Mark A. Peplow; Julia M. Rushton; Jonathan W. Steed; Surojit Sur

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
327 KB
Volume
8
Category
Article
ISSN
0947-6539

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## Abstract A new family of chiral phosphorus ligands (**5**) for use in enantioselective catalysis have been synthesised. The ligands contain the electron‐poor bis(sulfonyl)diazaphospholidine moiety and possess a highly modular structure which is well suited to the synthesis of a library. A small