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Phosphonium Ylides from Nucleophilic Addition of Triphenylphosphine to [26]Hexaphyrin(1.1.1.1.1.1)

✍ Scribed by Youfu, Katsuyuki; Osuka, Atsuhiro


Book ID
120986410
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
233 KB
Volume
7
Category
Article
ISSN
1523-7060

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## Abstract Treatment of hexakis(pentafluorophenyl)‐substituted [26]hexaphyrin(1.1.1.1.1.1) (**1**) with CuCl in the presence of pyridine and molecular oxygen led to formation of doubly N‐confused [26]hexaphyrin(1.1.1.1.1.1) **2** in a moderate yield through an unprecedented double pyrrolic rearran