Group 12 Metal Complexes of [26]Hexaphyrin(1.1.1.1.1.1)
β Scribed by Mori, Shigeki; Shimizu, Soji; Shin, Ji-Young; Osuka, Atsuhiro
- Book ID
- 126774782
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 160 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
## Abstract Treatment of hexakis(pentafluorophenyl)βsubstituted [26]hexaphyrin(1.1.1.1.1.1) (**1**) with CuCl in the presence of pyridine and molecular oxygen led to formation of doubly Nβconfused [26]hexaphyrin(1.1.1.1.1.1) **2** in a moderate yield through an unprecedented double pyrrolic rearran
## Abstract Conformational preference and chemical stability of __meso__βarylβsubstituted [26]hexaphyrins(1.1.1.1.1.1) ([26]ArH) depend upon __meso__βaryl substituents. Although only a planar and rectangular conformation (typeβII conformation) has been identified for [26]ArH so far, we have demonst