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Phosphonate vs. phosphinate elimination during olefination of aldehydes

✍ Scribed by Mahavir Prashad


Book ID
103406295
Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
181 KB
Volume
34
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Phosphonic systems. Part 15. Addition of
✍ Elmar L. Muller; Tomasz A. Modro πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 English βš– 470 KB

## Abstract Lithiated diethyl prop‐2‐enylphosphonate adds to an aliphatic or an aromatic aldehyde, yielding a diastereomeric mixture of the kinetically controlled α‐adduct. Upon warming, these adducts decompose back to starting materials to give finally the thermodynamically controlled γ‐adducts, o