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Phosphonic systems. Part 15. Addition of diethyl prop-2-enylphosphonate to aldehydes: Fragmentation vs. isomerization of kinetic products

✍ Scribed by Elmar L. Muller; Tomasz A. Modro


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
470 KB
Volume
5
Category
Article
ISSN
1042-7163

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✦ Synopsis


Abstract

Lithiated diethyl prop‐2‐enylphosphonate adds to an aliphatic or an aromatic aldehyde, yielding a diastereomeric mixture of the kinetically controlled α‐adduct. Upon warming, these adducts decompose back to starting materials to give finally the thermodynamically controlled γ‐adducts, or undergo fragmentation to diethyl phosphate and (E) dienes. The distribution of the first product between these two pathways is a function of the aldehyde (aromatic vs. aliphatic) and of steric interactions operating within the two diastereomers of the adduct.