Phosphinic acids and derivatives 6. Esters of dialkylphosphinic acids

✍ Scribed by Paul Haake; Robert D. Cook; Wolfgang Schwarz; D.R. McCoy

• Book ID: 104223023
• Publisher: Elsevier Science
• Year: 1968
• Tongue: French
• Weight: 222 KB
• Volume: 9
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)89834-2

✦ Synopsis

There has been considerable recent interest in alkylphosphinate esters as substrates for study of displacement at phosphorus. ~-4 Interpretation of some of this data is complicated by the problem of possible attack at alkyl carbon rather than phosphorus. We report here data on relative rates of hydrolysis in acyclic and cyclic compounds and elucidation of the position of attack by H1aO-in both series through use of no-enriched water.