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Phosphine–Alkene Ligands as Mechanistic Probes in the Pauson–Khand Reaction

✍ Scribed by Catalina Ferrer; Jordi Benet-Buchholz; Antoni Riera; Xavier Verdaguer


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
378 KB
Volume
16
Category
Article
ISSN
0947-6539

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ChemInform Abstract: Unexpected Regiocon
✍ L. M. HARWOOD; L. S. A. TEJERA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

Unexpected Regiocontrol in the Pauson-Khand Reaction due to 2-Furyl Substitution of the Alkene Component. -Vinylfurans (II) and (V) undergo regiocontrolled title reaction to furnish products (IV) and (VI), respectively. The intramolecular Pauson-Khand reaction of compound (VII) fails.