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ChemInform Abstract: Unexpected Regiocontrol in the Pauson—Khand Reaction due to 2-Furyl Substitution of the Alkene Component.

✍ Scribed by L. M. HARWOOD; L. S. A. TEJERA

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199802061

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✦ Synopsis

Unexpected Regiocontrol in the Pauson-Khand Reaction due to 2-Furyl Substitution of the Alkene Component.

-Vinylfurans (II) and (V) undergo regiocontrolled title reaction to furnish products (IV) and (VI), respectively. The intramolecular Pauson-Khand reaction of compound (VII) fails.

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