Phosphine-free polystyrene-supported palladium(II) complex as an efficient catalyst for the Heck and Suzuki coupling reactions in water
β Scribed by Mohammad Bakherad; Ali Keivanloo; Amir H. Amin; Saeideh Jajarmi
- Book ID
- 119222816
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 220 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1631-0748
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π SIMILAR VOLUMES
MCM-41-supported bidentate phosphine palladium(0) complex was conveniently synthesized from commercially available and cheap β₯aminopropyltriethoxysilane via immobilization on MCM-41, followed by reacting with diphenylphosphinomethanol and palladium chloride and then the reduction with hydrazine hydr
## Abstract Bis(imino)pyridine palladium(II) complexes 3 and 4 of type [PdCl(L)PF~6~] are found to be efficient catalysts for SuzukiβMiyaura reactions of aryl halides and arylboronic acids. The reactions proceed smoothly to generate the corresponding biaryl compounds in moderate to excellent yields