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Bis(imino)pyridine palladium(II) complexes as efficient catalysts for the Suzuki–Miyaura reaction in water

✍ Scribed by Ping Liu; Mei Yan; Ren He

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
247 KB
Volume
24
Category
Article
ISSN
0268-2605

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✦ Synopsis

Abstract

Bis(imino)pyridine palladium(II) complexes 3 and 4 of type [PdCl(L)PF~6~] are found to be efficient catalysts for Suzuki–Miyaura reactions of aryl halides and arylboronic acids. The reactions proceed smoothly to generate the corresponding biaryl compounds in moderate to excellent yields. The synthesis of various fluorinated biphenyl derivatives was successfully achieved by the complex 4 catalyzed the Suzuki–Miyaura reaction in the presence of surfactants bearing a long alkyl chain. Copyright © 2009 John Wiley & Sons, Ltd.

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## Iron(0), rhodium(I) and palladium(II) complexes with p-(N,N-dimethylaminophenyl) diphenylphosphine and the application of the palladium complex