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Phosphine Effects in the Copper(I) Hydride-Catalyzed Hydrogenation of Ketones and Regioselective 1,2-Reduction of α,β-Unsaturated Ketones and Aldehydes. Hydrogenation of Decalin and Steroidal Ketones and Enones

✍ Scribed by Jian-Xin Chen; John F. Daeuble; Jeffrey M. Stryker


Book ID
108370776
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
276 KB
Volume
56
Category
Article
ISSN
0040-4020

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Highly Chemoselective Catalytic Hydrogen
✍ Jian-Xin Chen; John F. Daeuble; Donna M. Brestensky; Jeffrey M. Stryker 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 310 KB

AbstractÐA base metal hydrogenation catalyst composed of the phenyldimethylphosphine-stabilized copper(I) hydride complex provides for the highly chemoselective hydrogenation of unsaturated ketones and aldehydes to unsaturated alcohols, including the regioselective 1,2-reduction of a,b-unsaturated k