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Phosphine dihalides as reagents for synthesis of tungsten aminomethylidyne complexes

✍ Scribed by Stephen Anderson; Darren J. Cook; Anthony F. Hill


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
166 KB
Volume
463
Category
Article
ISSN
0022-328X

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## Abstract Redox transmetallation reactions between trimethyltin compounds, SnMe~3~L [L = 3,5‐diphenylpyrazolate (Ph~2~pz), 2,6‐di‐__tert__‐butyl‐4‐methylphenolate (OAr), or C~6~F~5~] and lanthanoid metals have yielded [Ln(Ph~2~pz)~2~(DME)~2~] (Ln = Eu, Yb), [Ln(Ph~2~pz)~3~(DME)~2~] (Ln = Y, La, N