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Phosphato, Chromato, and Perrhenato Complexes of Titanium(IV) and Zirconium(IV) Containing Kläui's Tripodal Ligand

✍ Scribed by Yi, ; Zhang, Qian-Feng; Lam, Tony C. H.; Chan, Eddie Y. Y.; Williams, Ian D.; Leung, Wa-Hung

Book ID
126772614
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
208 KB
Volume
45
Category
Article
ISSN
0020-1669

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Titanium(IV) and Zirconium(IV) Sulfato C
Titanium(IV) and Zirconium(IV) Sulfato Complexes Containing the Kläui Tripodal Ligand: Molecular Models of Sulfated Metal Oxide Surfaces
✍ Qian-Feng Zhang; Tony C. H. Lam; Xiao-Yi Yi; Eddie Y. Y. Chan; Wai-Yeung Wong; H 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 544 KB

## Abstract Treatment of titanyl sulfate in about 60 mM sulfuric acid with NaL~OEt~ (L~OEt~^−^=[(η^5^‐C~5~H~5~)Co{P(O)(OEt)~2~}~3~]^−^) afforded the μ‐sulfato complex [(L~OEt~Ti)~2~(μ‐O)~2~(μ‐SO~4~)] (2). In more concentrated sulfuric acid (>1 M), the same reaction yielded the di‐μ‐sulfato complex