Half-Sandwich Titanium(IV) Complexes with Kläui's Tripod Ligand
✍ Scribed by Lam, Tony C. H.; Chan, Eddie Y. Y.; Mak, Wing-Leung; Lo, Samuel M. F.; Williams, Ian D.; Wong, Wing-Tak; Leung, Wa-Hung
- Book ID
- 126305015
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 161 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0020-1669
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📜 SIMILAR VOLUMES
## Abstract Treatment of titanyl sulfate in about 60 mM sulfuric acid with NaL~OEt~ (L~OEt~^−^=[(η^5^‐C~5~H~5~)Co{P(O)(OEt)~2~}~3~]^−^) afforded the μ‐sulfato complex [(L~OEt~Ti)~2~(μ‐O)~2~(μ‐SO~4~)] (2). In more concentrated sulfuric acid (>1 M), the same reaction yielded the di‐μ‐sulfato complex
## Abstract The ^47, 49^Ti chemical shifts, resonance line half‐widths (Δν~1/2~) and energies of the first electronic charge‐transfer transitions $(\lambda\_{\max}^{\rm 1.CT})$ of Cp′TiX~3~, where Cp′ = η^5^‐C~5~H~5~ (Cp), η^5^‐C~5~H~4~Me (MeCp), η^5^‐C~5~HMe~4~ (Me~4~Cp), η^5^‐C~5~Me~5~ (Me~5~Cp),